There isn't any, its an unsubstantiated claim - firstly its a decoupling cap, secondly its used at a fixed DC voltage, so why would you need bipolar?This is all they say. Hopefully, someone around here can give us a technical explanation.
Read Cyril Bateman's capacitor articles on Linear Audio. Bipolar caps are preferred even in power supply applications. My Dac, Preamp, and Phono stages have only 24 N and 56 NX bipolar Blackgates as local power supply bypasses - all direct coupled jfet/Fet solid state, even the regulators are jfet/ Fet shunts with BG bipolars bypassing the LED voltage references. The power amp has over 90,000 uf of Blackgate including 4 of the 2,200 uf/100 V N series bipolars - one on each rail.